Hi
Robert ~
If there is no 5V, then the VIN will be 0V. It can not open the MOS Q4. So there is NO reading from A4_PA05_AIN5/VBAT.
If you want to read it with 5V power supply, you have to short the R56 which is NDP(NO not place this moment).

Thanks
best rgds
Bill

Thanks
best rgds
Bill